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Cyclohexane: Isomers & Synthesis

Lesson Transcript
Instructor: Korry Barnes

Korry has a Ph.D. in organic chemistry and teaches college chemistry courses.

Cyclohexane is an important organic compound that can appear as different isomers, or arrangements of molecules. Discover the chemical composition of cyclohexane, its different isomers, and how chemists can synthesize the compound in a lab. Updated: 01/11/2022

Roller Coasters & Molecules

Are you one of those people that likes riding on roller coasters at the theme park? Have you ever been on one that goes upside down in a loop? In general, a loop can kind of be thought of as a cycle of sorts.

Did you know that some organic compounds can be referred to as cyclic and kind of resemble a loop of sorts? These types of compounds result when we take two ends of a molecule and bond the ends together to create the cycle or loop, very similar to a loop on a roller coaster. The topic of this lesson is a specific kind of loop known as cyclohexane. We will be studying the derivatives and isomers of cyclohexane as well as how they can be synthesized in the lab. Let's go around the loop!

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  • 0:04 Roller Coasters & Molecules
  • 0:46 What Is Cyclohexane?
  • 1:05 Isomers of Cyclohexane
  • 2:34 Cycolhexane Isomer Synthesis
  • 3:56 Lesson Summary
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What Is Cyclohexane?

Cyclohexane is an organic compound that is composed of carbon and hydrogen atoms and is a cyclic structure with the ring being constructed of six carbon atoms bonded together. The bonds in cyclohexane are all single bonds, and the shape resembles a hexagon when it's drawn as a bond-line structure.

Cyclohexane is a cyclic organic compound composed of six carbon atoms and contains only single bonds

Isomers of Cyclohexane

Although cyclohexane is an important compound, it gets more interesting when we start to decorate the ring with other substituents (atoms or groups of atoms). This results in derivatives and isomers of cyclohexane. For example, let's consider both 1,2-dichlorocyclohexane and 1,4-dichlorocyclohexane.

Notice how both compounds contain a cyclohexane ring and each have two chlorine atoms. They differ in how the chlorine atoms are bonded to the ring. This type of relationship represents what are called constitutional isomers, which are compounds that have the same type and number of atoms but differ in the way the atoms are bonded to one another. Another way of stating it is that the compounds have the same chemical formulas but different atom connectivity.

1,2- and 1,4-dichlorocyclohexane are constitutional isomers of one another

What if we had a case in which the cyclohexane ring had two alcohol (-OH) groups that were bonded to the same positions on the ring, but they had a different spatial orientation relative to one another? Isomers of a compound that differ only in their three-dimensional (spatial) orientation are called stereoisomers. This is the case with cis-1,2-dihydroxycyclohexane and trans-1,2-dihydroxycylohexane. Notice how the two alcohol groups are on the same face of the ring in one case (two dashed bonds) but are on opposite faces (one wedged bond, one dashed bond) in the other.

Isomers that differ from one another by their three-dimensional orientation are called stereoisomers

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