What is Iron?
Iron Compounds
Iron makes up much of earth's inner and outer core. In fact, 5% of the earth's crust is made of iron! The most common rocks that contain iron are:
- Hematite {eq}Fe_2O_3 {/eq}.
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- Greenalite {eq}(Fe^{+2},Fe^{+3})_{2-3}Si_2O_5OH_4 {/eq}.
- Magnetite {eq}Fe_3O_4 {/eq}.
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- Taconite, which are pellets of low-grade iron ore.
Not only is iron a common substance on earth but also abundantly available in the sun and stars. Iron fragments were deposited on earth when a dying star erupted massively many billions of years ago. Now, what is iron? Is iron a molecule? A chemical substance? Is iron a compound?
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Iron is a lustrous gray metal that is found in group number 8 and period 4 on the periodic table. Iron's chemical name is ferrum, from the Latin word ferrium. This is how iron got Fe as its symbol. The format of nonmetal elements formula with iron is Fe X, where X is a nonmetal element or compound. The number of protons in iron's nucleus is 26, which makes its atomic number also 26. Its electron configuration is {eq}[Ar] 3d^6 2s^2 {/eq}. There are six electrons in its d orbital and two electrons in the s orbital, that means its outermost shell has a total of eight electrons. Notice that the d orbital is partially filled. They normally can hold a total of ten electrons, but the d orbitals in iron only hold six electrons. This is a good enough indication to tell that iron is a transition metal. Iron is categorized according to its oxidative state into:
- Ferrous compounds ({eq}Fe^{+2} {/eq}), also known as bivalent iron (II) compounds.
- Ferric compounds ({eq}Fe^{+3} {/eq}), also known as trivalent iron (III) compounds.
Ferric and ferrous are the major types of iron compounds. Before proceeding to the sections that provide more information about these compounds, the reader is advised to examine the table that documents many of iron's important properties.
Parameter | Data |
---|---|
Physical State | Solid at room temperature |
Boiling Point | 2861C |
Melting Point | 1538C |
Density | 7.874 g/cm3 |
Oxidative State | +2,+3 |
Atomic Mass | 55.845u |
Ferrous Compounds
As mentioned in the earlier section, the type of iron compound is dependent on the oxidative state of iron itself. The oxidative state is an atom's oxidation number, which is a number that refers to the number of electrons an atom gains or loses, when it forms chemical bonds with other atoms. The type of chemical bond such atoms form is an ionic bond, which involves the complete transfer of one or more electrons from one atom to another. An electrostatic attraction is formed when ions form these bonds. The ion that has the ability to liberate the electrons from its outermost shell is called cation. And the ion that has the ability to accept the electrons are called anions. Cations are positively charged ions; they have more protons than they do electrons. Anions are negatively charged ions; they have more electrons than they do protons. Figure 4 shows how ionic bonds are formed through the complete transfer of electrons from the cation to the anion.
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Iron has a variable oxidative state; its oxidation number can be +2 or +3 depending on the compound it's going to form. The reason why this element has multiple oxidation numbers is because it is a transition metal. In the case of ferrous compounds, the oxidation number of iron is +2. {eq}Fe^{+2} {/eq} is known as the ferrous cation. This means iron must transfer two of its electrons to another element/compound when it forms ferrous compounds. Ferrous compounds are known to have a pale green shade. The following is a list of ferrous compounds:
- Ferrous oxide\iron (II) oxide {eq}FeO {/eq}: {eq}cation \: Fe^{+2} \: anion \: O^{-2} {/eq}
- Ferrous phosphate\iron (II) phosphate {eq}Fe_3 (PO_4 )_2 {/eq}: {eq}cation \: Fe^{+2} \: anion \: PO_4^{-3} {/eq}.
- Ferrous nitrate\iron (II) nitrate: {eq}Fe (NO3 )_2 {/eq}: {eq}cation \: Fe^{+2} \: anion \: NO_3^{-1} {/eq}.
- Ferrous sulfate\iron (II) sulfate {eq}FeSO_4 {/eq}: {eq}cation \: Fe^{+2} \: anion \: SO_4^{-2} {/eq}.
- Ferrous chloride\iron (II) chloride {eq}FeCl_2 {/eq}: {eq}cation \: Fe^{+2} \: anion \: Cl^{-1} {/eq}.
Ferric Compounds
When iron's oxidative state is +3, it gives up three of its outermost electrons to form ferric compounds. The iron ions in these compounds are called ferric cations. The color of ferric compounds tend to be brownish or rust-like. The following is a list of ferric compounds:
- Ferric chloride\iron (III) chloride {eq}FeCl_3 {/eq}: {eq}cation \: Fe^{+3} \: anion \: Cl^{-1} {/eq}.
- Ferric oxide\iron (III) oxide {eq}Fe_2O_3 {/eq}: {eq}cation \: Fe^{+3} \: anion \: O^{-2} {/eq}.
- Ferric sulfate\iron (III) sulfate {eq}Fe_2(SO_4)_3 {/eq}: {eq}cation \: Fe^{+3} \: anion \: SO_4^{-2} {/eq}.
- Ferric phosphate\iron (III) phosphate {eq}FePO_4 {/eq}: {eq}cation \: Fe^{+3} \: anion \: PO_4^{-3} {/eq}.
Uses of Iron
The many uses of iron are too versatile to mention. It is used in the manufacturing of steels which are used in various applications, including pipes and reactor vessels in chemical plants. Pure iron isn't used all by itself of course. It is often mixed with other materials depending on the equipment that's going to be manufactured. Iron steel is often mixed with alloys like nickel, chromium, and manganese. These alloy steels are used in constructing bridges, chains, and the list goes on. Combining iron steel with such alloys makes the steel extremely resistant to corrosion, which is why alloy steels are used in chemical plants when highly corrosive substances are put in the equation. That's the general uses of iron. The next question is: what does ferrous sulfate do? What does the ferrous and ferric iron compounds mentioned earlier do? The answer is provided in the following list:
- Ferrous sulfate {eq}FeSO_4 {/eq} is used in the pharmaceutical industry. It is used in medicine to treat iron deficiency.
- Ferrous nitrate {eq}Fe (NO3 )_2 {/eq} is used as a corrosion inhibitor and as a reagent in various chemical reactions.
- Ferrous phosphate {eq}Fe_3(PO_4)_2 {/eq} is used as a pesticide in farms and agriculture.
- Ferrous chloride {eq}FeCl_2 {/eq} is used in the pharmaceutical industry and in wastewater treatment.
- Ferric oxide {eq}Fe_2O_3 {/eq} is used as a glass polishing agent and in paints. It is also used as a UV blocking agent.
- Ferric sulfate {eq}Fe_2(SO_4)_3 {/eq} is used in dermatology and in dentistry.
- Ferric chloride {eq}FeCl_3 {/eq} is used in sewage treatment and in purifying water.
Plant Use of Iron
Iron is extremely important when it comes to the plant's production of chlorophyll. Chlorophyll is the chemical located in the plant's leaves, in their chloroplasts specifically. Plants usually appear green because chlorophyll reflects the green wavelengths of light instead of absorbing it. Plants show that they are suffering from iron deficiency through the color of their leaves; green leaves are rich with chlorophyll and iron, yellow or pale leaves do not have the sufficient amount of chlorophyll. Deficiency in chlorophyll doesn't just make plants less fresh, it disrupts the plant's growth.
Plants need iron to produce enough energy to grow. Iron isn't sprinkled over the plants' leaves; most of the iron plants absorb is available in the soil, along with other minerals. Plants may still suffer from iron deficiency in spite of that fact that the soil is rich with ferric oxide. That is because plants do not absorb iron from ferric oxide well, which is why fertilizers are used. Fertilizers contain iron sulfates, which is a source of iron that plants absorb very well even at high pH levels or cold temperatures.
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Lesson Summary
Iron (Fe) is the fourth most abundant element found on earth. It is a metal in group 8 and period 4 on the periodic table. Iron is a transition metal, which is why it has multiple oxidative states. An atom's oxidation number shows the number of electrons it can gain or lose when forming ionic bonds with other elements/compounds. The type of iron compounds formed is dependent on the oxidation number of iron. If its oxidation number was +2 then ferrous compounds are formed, where the ferrous cation {eq}Fe^{+2} {/eq} bonds with a nonmetal anion. If its oxidation number was +3 then ferric compounds are formed, where the ferric cation {eq}Fe^{+3} {/eq} bonds with a nonmetal anion.
Iron is an essential metal in life. It is used in manufacturing buildings, bridges, equipment as well as in agriculture. Plants need iron to form chlorophyll. In spite of the soil being rich with ferric oxide, which is an iron source, plants struggle in absorbing it which leads to a disruption in their growth. Which is why iron sulfates are used in fertilizers; they are a source of iron that plants can absorb with ease even at high pH levels and low temperatures.
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What are the uses and applications of iron?
Iron is used in construction, pharmaceuticals, agriculture, and water treatment. It is used in the manufacturing of many types of alloy steels and stainless steels, which are used in buildings, industrial plants, and in construction. Some iron compounds are used in sewage water treatment and in water purification.
Is iron a compound or not?
Iron by itself is not a compound, it is an element. Iron can form various compounds. The types of compounds iron makes depends on its oxidative state. If its oxidation number was +2 then it makes ferrous compounds. If its oxidation number was +3 then it makes ferric compounds.
What is the element name of Fe?
The name of the element with the chemical symbol Fe is iron. The symbol Fe is derived from its Latin name, Ferrium. Iron is a transition metal in group 8 and period 4 on the periodic table.
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