Table of Contents
- What is Radioactive Decay?
- Types of Radioactive Decay
- Radioactive Decay Formula
- Radioactive Decay Examples
- Lesson Summary
To understand radioactive decay definition, recall that nuclide is a nucleus with a specific neutron number N and atomic number or number of protons Z, therefore, a specific mass number A=N+Z. Nuclides can be stable and unstable. So, to know what is radioactive decay, it is the case when the unstable nuclides emit particles or electromagnetic radiations and turn to other nuclides. In some nuclides, the continuous process of radioactive decaying takes less than a microsecond, but in some other nuclides, it may continue to radioactive decay for billions of years. Keep in mind that an unstable radioactive nuclide loses its mass while emitting particles.
The famous physicists Marie Curie and Ernest Rutherford, among many others, discovered that radioactive decay results in positive and negative particles and neutral rays. Due to the different penetration characteristics, the three results were given the names alpha decay, beta decay, and gamma decay. So, when an unstable nuclide starts emitting radioactive materials, it is called the parent nucleus, and the result new nuclide is called the daughter nucleus. Every nuclide can be represented as {eq}_{Z}^{A}\textrm{X} {/eq} where the symbol of any nuclide replaces X, A is the atomic mass, and Z is the number of protons. Keep in mind that A=Z+N, where N is the number of neutrons.
Due to mass-energy conservation laws during decay, the unstable parent and the result daughter nuclides are related by their atomic mass numbers A and atomic numbers Z. So, The parent's atomic number must be equal to the daughter's atomic number plus the emitted particle atomic number. Also, the parent's atomic mass number must equal the daughter's atomic mass number plus the emitted particle atomic mass number.
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The helium nucleus {eq}_{2}^{4}\textrm{He} {/eq} is called an alpha particle which is made of two protons and two neutrons. In alpha decay or alpha emission, the unstable parent nuclide emits an alpha particle.
An example of alpha emission is the radioactive Radium nuclide Ra-226 turning to Radon Rn-222 by emitting an alpha particle:
{eq}_{88}^{226}\textrm{Ra}\rightarrow _{86}^{222}\textrm{Rn}+_{2}^{4}\textrm{He} {/eq}
The atomic mass and numbers are balanced in this radioactive process. Notice that, {eq}A_{Parent}=A_{Daughter}+A_{Particle} {/eq} or {eq}226=222+4 {/eq}. Also, {eq}Z_{Parent}=Z_{Daughter}+Z_{Particle} {/eq} or {eq}88=86+2 {/eq}
So, in alpha decay, the atomic mass number A is reduced by four, and the atomic number Z is reduced by 2.
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There are two types of beta decay or beta emission: beta-minus decay and beta-plus or positron decay. Beta-minus {eq}\beta ^{-} {/eq} particle is an electron {eq}_{-1}^{0}\textrm{e} {/eq}. Beta-plus or positron {eq}\beta ^{+} {/eq} is the opposite particle to an electron in terms of the charge or the proton.
Example 1:
An example of beta-minus decay or emission is the radioactive Cobalt nuclide Co-40 turning to Nickle Ni-40 by emitting an electron:
{eq}_{27}^{40}\textrm{Co}\rightarrow _{28}^{40}\textrm{Ni}+\beta^{-1} {/eq}
The atomic mass and numbers are balanced in this radioactive process. Notice that, {eq}A_{Parent}=A_{Daughter}+A_{Particle} {/eq} or {eq}40=40+0 {/eq}. Also, {eq}Z_{Parent}=Z_{Daughter}+Z_{Particle} {/eq} or {eq}27=28+(-1) {/eq}
So, in beta-minus decay, the atomic mass number A stays the same, and the atomic number Z increases by 1. The daughter nucleus in beta-minus decay has a larger mass than the parent nucleus.
Example 2:
An example of beta-plus decay or emission is the radioactive Carbon nuclide C-11 turning to Boron B-11 by emitting a positron:
{eq}_{6}^{11}\textrm{C}\rightarrow _{5}^{11}\textrm{B}+\beta^{+1} {/eq}
The atomic mass and numbers are balanced in this radioactive process. Notice that, {eq}A_{Parent}=A_{Daughter}+A_{Particle} {/eq} or {eq}11=11+0 {/eq}. Also, {eq}Z_{Parent}=Z_{Daughter}+Z_{Particle} {/eq} or {eq}6=5+1 {/eq}
So, in beta-plus or positron decay, the atomic mass number A stays the same, and the atomic number Z is decreased by 1. The daughter nucleus in positron decay has a smaller mass than the parent nucleus.
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Recall that a photon is a sack or bundle of energy with no mass and no charge, which makes up electromagnetic waves. For example, light is believed to be dual-natured, one of which is looked at as photon waves. Gamma rays are another name for photons. In gamma {eq}\gamma {/eq} emission or decay energy is released as gamma-ray photons or electromagnetic waves when an excited nuclide moves to a more stable or less excited state. In general, other decays involve releasing energy or emitting gamma rays.
Example:
An example of gamma decay or emission is the excited radioactive Protactinium nuclide Pa-234 turning to less excited Protactinium Pa-234 by emitting a gamma-ray photon:
{eq}_{}^{234}\textrm{Pa}{}^{*}\rightarrow _{}^{234}\textrm{Pa}+\gamma {/eq}
Notice that star (*) refers to the excited state. Also, both parent and daughter nuclei are the same element since gamma rays have no atomic mass or atomic number.
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The radioactive decay formula is given by:
where N(t) is the number of remaining nuclei at time t measured in seconds (S), N(0) is the initial number of nuclei at time t=0, and {eq}\lambda {/eq} is the decay constant that differs for different nuclides and is measured by 1/seconds or 1/S (S^{-1})
The radioactive decay equation shows that the number of nuclei is reduced exponentially by time so that the formula can be written as {eq}\frac {N(t)}{N(0)}=e^{-\lambda *t} {/eq}
To know how to calculate radioactive decay, use the known values of the initial amount to nuclei at t=0 and the decay constant of the unstable element, then at any time t by substituting all values in the formula, one can find out how many of the element's nuclei are left N(t).
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In particle physics, lifetime is the life of an unstable particle or nucleus while it is still active. In general, lifetime is referred to as {eq}T_{mean} {/eq} which is equal to {eq}\frac {1}{ \lambda} {/eq} or the reciprocal of the decay constant.
So, lifetime formula is: {eq}T_{mean}=\frac {1}{ \lambda} {/eq}, or decay constant formula is: {eq}\lambda=\frac {1}{ T_{mean}} {/eq}
A decaying radioactive material follows the formula: {eq}-\frac{\mathrm{d} N(t)}{\mathrm{d} t}=\lambda *N(t) {/eq} where the minus sign refers to the decaying or decrease in the number of nuclei N(t) over time. So, the radioactive mass is reduced exponentially following the formula: {eq}N(t)=N(0)*e^{-\lambda *t} {/eq}.
Consider the case that the amount of radioactive material is reduced to half its initial amount. For example, consider at time t where the current N(t)=25g, as half the initial N(0)=50g. The time that has passed till half as much remains of the radioactive material is called half-life decay.
Now, substituting {eq}N(t)=(\frac {1}{2})*N(0) {/eq} or {eq}\frac {N(t)}{N(0)}={1/2} {/eq} in the exponential formula of N(t) gives: {eq}{1/2}=e^{-\lambda *t} {/eq}. Simplifying the formula to get the time t in terms of the decay constant {eq}\lambda {/eq} gives: {eq}T_{1/2}=\frac {ln2}{\lambda}=\frac {0.693}{\lambda} {/eq}.
{eq}T_{1/2} {/eq} is called the half-life decaying time it took the decaying radioactive material to lose half its initial mass.
So, half-life radioactive decay formula is given by:
Recall that the mean lifetime is related to decay constant by the formula: {eq}T_{mean}=\frac {1}{ \lambda} {/eq}, so in terms of the mean lifetime, the half life radioactive decay formula can be written as: {eq}T_{1/2}=ln2*T_{mean}=0.693*T_{mean} {/eq} or {eq}T_{mean}=\frac {T_{1/2}}{0.693} {/eq}.
Dating the archaeological and geological specimens are radioactive decay examples. To know the age of a specimen, the unstable isotope Carbon fourteen {eq}_{}^{14}\textrm{C} {/eq} is widely used.
Example 1:
Carbon-14's half-life is known to be 5730 years.
1- What is the carbon-14 decay constant?
2- if the carbon-14 activity was recorded at {eq}0.255 S^{-1} {/eq}, how many atoms were there?
3- if the ratio N(t)/N(0)=0.379 when the activity of carbon-14 died, how old was the specimen?
Solution:
1- Use the half life radioactive decay formula: {eq}T_{1/2}=\frac {0.693}{\lambda} {/eq}, but do not forget to convert numbers to SI units.
Recall that 1 year=1*365 days*24 hours*60 minutes*60 seconds={eq}3.156*10^{7} {/eq} Second T_{1/2}=5730 years={eq}5730*3.156*10^{7} {/eq}={eq}1.808*10^{11} {/eq}
S (4 significant figures)
So, the decay constant for {eq}_{}^{14}\textrm{C} {/eq} is equal to: {eq}\lambda=\frac {0.693}{T_{1/2}}=0.693/1.808*10^{11}=3.83*10^-{12} s^{-1}{/eq} .
2- Use the formula: {eq}-\frac{\mathrm{d} N(t)}{\mathrm{d} t}=\lambda *N(t) {/eq} where {eq}-\frac{\mathrm{d} N(t)}{\mathrm{d} t}=0.255 s^{-1} {/eq} . Substitute the value of decay constant for carbon-14 to find that:
{eq}0.255=3.83*10^-{12}*N(t) {/eq} and {eq}N(t)=0.255/3.83*10^-{12}=6.65*10^{10} {/eq} atoms.
3- Use the radioactive decay formula: {eq}N(t)=N(0)*e^{-\lambda *t} {/eq} where N(t)/N(0)=0.379, so:
{eq}0.379=e^{-\lambda *t} {/eq}.
Taking the logarithm of both sides gives: {eq}ln (0.379)={-\lambda *t} {/eq} and the specimen age t is equal to: {eq}t=\frac {ln (0.379)}{-\lambda}=\frac {-0.97}{-3.83*10^-{12}}=2.53*10^{11} {/eq} s. Converting this number to years may give a better idea of how old is the specimen. So, divide to get: {eq}t=\frac {2.53*10^11}{365 days*24 hours*60 minutes*60 seconds}=8020 {/eq} years.
Example 2:
The half-life of Cobalt-60 is approximately 5.7 years. How much is left of 20 mg of cobalt-60 is left after ten years?
Solution:
Use the radioactive decay formula: {eq}N(t)=N(0)*e^{-\lambda *t} {/eq} and substitute values.
N(0)=20 mg=20*10^{-3} g
t=10 years= 10*3.156*10^{7}=3.156*10^{8} Second
the decay constant is calculated by the formula: {eq}\lambda=\frac {0.693}{T_{1/2}}=\frac {0.693}{5.7*3.156*10^{7}}=3.9*10^{-9} {/eq} s
So, the amount of atoms left after ten years is: {eq}N(t)=20*10^{-3}*e^{-(3.9*10^{-9})*(3.156*10^{8})}=0.02*e^{-1.23}=5.8*10^-3 {/eq} grams. Or there is 5.8 mg left of the initial 20 mg cobalt-60 after ten years of continuous radioactivity.
Recall that in gamma emission, energy is released when radioactive material is in an excited state. So, an example of gamma decay equation is:
{eq}_{}^{60}\textrm{Co}{}^{*}\rightarrow _{}^{60}\textrm{Co}+\gamma {/eq}
where the star refers to an excited state of the radioactive nuclide.
another example is:
{eq}_{}^{113}\textrm{In}{}^{*}\rightarrow _{}^{113}\textrm{In}+\gamma {/eq}
In general, {eq}_{}^{}\textrm{X}{}^{*}\rightarrow _{}^{}\textrm{X}+_{0}^{0}\textrm{ \gamma} {/eq}
where {eq}_{0}^{0}\textrm{ \gamma} {/eq} is the gamma rays that have no atomic mass and no atomic number but are bundles of photons or energy. In general, gamma rays are written as {eq}\gamma {/eq}.
Radioactive decay is defined as the particles or electromagnetic waves emitted once an unstable nuclide move to a less excited or more stable state. There are three well-known radioactive decays: alpha decay, beta decay, and gamma decay. In both alpha and beta decay, the daughter nucleus is different from the parent nucleus. However, in gamma-ray decay, both parent and daughter nuclei are the same element, but the parent is in a more excited state. When a radioactive material starts decaying, its mass is reduced exponentially and can be calculated by the formula of radioactive decay: {eq}N(t)=N(0)*e^{-\lambda *t} {/eq} where {eq}\lambda {/eq} is the decay constant. The mean lifetime is how long an unstable nuclide stays radioactive. Lifetime is calculated by the formula: {eq}T_{mean}=\frac {1}{ \lambda} {/eq}. Half-life is the time that an initial amount of radioactive material takes to reduce it half as much and is given by the formula: {eq}T_{1/2}=\frac {0.693}{\lambda} {/eq}.
Carbon dating is a famous application of the radioactive decay formula where the use of carbon-14 helps to know the age of an archaeological or geological specimen. In alpha decay, radioactivity involves emitting an alpha particle with two protons and two neutrons. Beta-minus decay involves emitting an electron that has a -1 charge. However, beta-plus or positron decay involves emitting the positive particle of the proton. Gamma decay usually accompanies other decays.
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Radioactive decay means that an unstable nuclide emits particles or rays and turns into another nuclide. The unstable nuclide is called the parent nucleus, and the result of radioactivity is called the daughter nucleus. Depending on the nuclide, radioactive decay may last from less than a microsecond to billions of years.
Half-life is the time it takes an initial amount of radioactive material to be reduced to its half. The half-life formula is given as:
T_{1/2}=\frac {0.693}{\lambda}
where \lambda is the decay constant
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